Preparation and investigation of complexes (bisazo)- imidazole with Co(II) and Cu(II).

Abstract


Hawraa Mehdi Farhan

In this study, transition metal complexes of Co(II) and Cu(II) with a newbisazo dye (2-(4- methoxy-2-(4- methoxy phenyl)diazenyl)phenyl)diazenyl)-4,5-diphenylimidazole were synthesized and characterized by elemental analysis, electronic data, FT-IR, 1 H-NMR, 13C-NMR, HMBC, HQSY and molar conductivity measurements. It has been found that the bisazo ligand behaves as tridentate (N,N',N") donor ligand forming chelates with (1:2) (metal: ligand) stoichiometry.

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