Abstract

J. R. Dhellot*, E.Matouba , M.G. Maloumbi , J.M Nzikou, M.G. Dzondo ,M.Linder, M.Parmentier, S. Desobry

With the aim of diversifying the lipids sources eaten by the African populations and those of Congo Brazzaville in particular, a physicochemical study of Solanum nigrum L seeds was carried out and three chemical methods (Soxhlet, Bligh and Dyer, and Folch) were used to extract the oil. The dry matter content of the seeds is 94.22%. Average lipids content varies between 34.5 and 37.5% dry matter, proteins content is 17% dry matter and crude ash content averages 7.18% dry matter and the principal mineral element is Mg (180 mg/100g). The acid value of the oil is about 2.5, saponification value varies between 157.3 and 190.1, peroxide value is low at 5.13 and iodine is 102.33.The fatty acid compositions of S. nigrum seeds oil shows that it has 67.9% of linoleic acid, indicating its high unsaturation. Apart from linoleic acid, other prominent fatty acids were palmitic, stearic and oleic acids. The following average profile is: 18: 2n-6 > 18: 1 n-9 > 16: 0 > 18: 0. The oil is liquid at room temperature and green in colour. Oil viscosity varies between 20 and 35 mPa.s at 25°C. Three activation energies which vary between 0.8 to 26.58 kJ.mol-1 were determined using Arrhenius’s equation. The melting points estimated by Differential Scanning Calorimetry were found to be between -22.0 and -12.0°C for the Soxhlet and Folch-extracted oils. Bligh and Dyer oil have three melting points at -36.2, -15.2 and 33.7°C.